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Obsidian is a strongly protective stone, forming a shield against emotional negativity. It grounds you to the earth through the base chakra and strengthens you in times of need. It is helpful to highly sensitive people. It blocks psychic attack and removes negative spiritual influences.
Place obsidian by your bed or under the pillow to draw out mental stress and tension, it may have a calming effect but it will also highlight the cause of the stress. The cause must be redressed before peace can return, this will resolve the problem permanently rather than just having a palliative effect.